GEORGIA GULF CORPORATION -- METHANOL -- 6810-00-224-8353
===================== Product Identification ===================== Product ID:METHANOL MSDS Date:06/01/1999 FSC:6810 NIIN:00-224-8353 === Responsible Party === Company Name:GEORGIA GULF CORPORATION Box:629 City:PLAQUEMINE State:LA ZIP:70765-0629 Country:US Info Phone Num:225-687-8630 Emergency Phone Num:225-687-8630/685-2640 Preparer's Name:STEVE L. VARNADO Chemtrec Ind/Phone:(800)424-9300 CAGE:TO200 === Contractor Identification === Company Name:GEORGIA GULF CORPORATION Address:400 PERIMETER CENTER TER SUITE 595 Box:105197 City:ATLANTA State:GA ZIP:30348 Country:US Phone:504-685-2500/770-395-4500 GOOD# CAGE:49960 Company Name:GEORGIA GULF CORPORATION Address:Box:629 City:PLAQUEMINE State:LA ZIP:70765-0629 Country:US Phone:225-687-8630 CAGE:TO200 Company Name:JEM SALES INC INCHEMCO DIV Address:430 LAVENDER DR Box:City:ROME State:GA ZIP:30165-2262 Country:US Phone:706-232-1709 CAGE:0AZD7 ============= Composition/Information on Ingredients ============= Ingred Name:METHANOL CAS:67-56-1 RTECS #:PC1400000 > Wt:99.85 Other REC Limits:NONE RECOMMENDED OSHA PEL:260 MG/M3;200 PPM ACGIH TLV:262 MG/M3;200 PPM ACGIH STEL:328 MG/M3;250 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 5,600 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: EYE, SKIN, CENTRAL NERVOUS SYSTEM, LUNG, GI TRACT (HMIS). ACUTE - INGESTION OR INHALATION MAY PRODUCE HEADACHE, WEAKNESS, DROWSINESS, NAUSEA, VOMITING, EYE IRRITATION AND BLURRED VISION . SYMPTOMS MAY DISAPPEAR, THEN RELASPE. VISUAL DISTURBANCES UP TO AND INCLUDING BLINDNESS ALMOST ALWAYS OCCUR DURING RELASPE. LIVER TOXICITY MAY ALSO OCCUR. METHANOL CAN DEFAT SKIN CAUSING DERMATITIS. CHRONIC EFFECTS - METHANOL EXPOSURE CAN RESULT IN HEADACHE, DIZZINESS, WEAKNESS, DROWSINESS, NAUSEA, VOMITING, VERTIGO, CHILLS, DERMATITIS, EDEMA OF ARMS, GASTRIC PAIN, INSOMNIA, BLURRED VISION, DOUB LE VISION, BLINDNESS, NUMBNESS OF SKIN. Explanation of Carcinogenicity:THIS CHEMICAL IS NOT CONSIDERED TO BE CARCINOGENIC BY OSHA, NIOSH, NTP, IARC OR EPA. Effects of Overexposure:HEADACHE, WEAKNESS, DROWSINESS, LIGHTHEADEDNESS, DRUNKENNESS, NAUSEA, VOMITING, IRRITATION, BLURRED VISION, DEFATTING OF SKIN, DERMATITIS, DIZZINESS, VERTIGO, CHILLS, EDEMA OF ARMS, GASTRIC PAIN, INSO MNIA, DOUBLE VISION, NUMBNESS OF SKIN. THERE IS USUALLY A LATENCY PERIOD DURING WHICH THE ACUTE SYMPTOMS MAY DISAPPEAR, THEN RELAPSE. VISUAL DISTURBANCES UP TO AND INCLUDING BLINDNESS ALMOST ALWAYS O CCUR DURING THE RELAPSE. Medical Cond Aggravated by Exposure:PERSONS WITH EXISTING SKIN, LIVER, KIDNEY OR EYE DISORDERS MAY BE AT INCREASED RISK WHEN EXPOSED TO METHANOL. METHANOL MAY ENHANCE THE TOXICITY OF CARBON MONOXIDE. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF ROOM TEMPERATURE WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER LIDS. GET IMMEDIATE MEDICAL ATTENTION. SKIN: PROMPTLY REMOVE CONTAMINATED CLOTHING AND WA SH SKIN WITH SOAP AND WATER FOR 15 MINUTES. SYSTEMIC EFFECTS MAY BE DELAYED. KEEP INDIVIDUAL UNDER OBSERVATION. INGESTION: IF PERSON IS CONSCIOUS, INDUCE VOMITING IMMEDIATELY, THEN GIVE 2 TEASPOONS OF BAKING SODA IN A GLASS OF WATER. GET MEDICAL ATTENTION IMMEDIATELY. INHALATION: MOVE EXPOSED PERSON TO FRESH AIR AT ONCE AND CALL EMERGENCY MEDICAL CARE.. IF NOT BREATHING, GIVE ARTIFICAL RESPIRATION . IF BREATHING IS DIFFICULT, GIVE OXYGEN ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=11.C, 51.8F Autoignition Temp:=464.C, 867.2F Lower Limits:6 Upper Limits:36 Extinguishing Media:SMALL FIRE: HALON REPLACEMENTOR CARBON DIOXIDE EXTINGUISHERS PR ALCOHOL FOAM. LARGE FIRE: ALCOHOL FOAM. WATER SPRAY OR FOG CAN COOL FIRE BUT MAY NOT BE EFFECTIVE TO EXTINGUISH FIRE. Fire Fighting Procedures:KEEP UNNECESSARY PEOPLE AWAY; ISOLATE AREA. AVOID BREATHING VAPORS, STAY UPWIND. WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING RESPIRATOR IN POSITIVE PRESSURE MODE AND CHEMICAL PROTECTIVE CLOTHING SPEC IFICALLY RECOMMENDED FOR METHANOL. USE WATER SPRAY TO COOL CONTAINERS EXPOSED TO FIRE. STAY AWAY FROM ENDS OF TANKS. Unusual Fire/Explosion Hazard:CONTAINER MAY EXPLODE. WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE. ISOLATE FOR 1/2 MILE IF TANK CAR/TRUCK IS INVOLVED IN FIRE. DANGEROUS FIRE AND EXPLOSION HAZARD. METHANO L IS EXTREMELY FLAMMABLE AND FORMS EXPLOSIVE MIXTURE WITH AIR. MAY TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:SHUT OFF IGNITION SOURCES. NO SMOKING IN SPILL AREA. ALLOW ONLY TRAINED PERSONNEL WEARING NIOSH APPROVED SUPPLIED AIR RESPIRATOR IN SPILL AREA. DO NOT TOUCH SPILL. STOP LEAK IF POSSIBLE. IF FIRE POTEN TIAL EXISTS, COVER SPILL WITH FOAM. PREVENT METHANOL ENTERING SEWERS SMALL SPILLS: TAKE UP WITH SAND OR NON-COMBUSTIBLE ABSORBENT AND PLACE INTO CONTAINERS FOR DISPOSAL. CONTROL LARGE SPILLS BY DIKING ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN WELL VENTILATED PLACE IN ACCORDANCE WITH 29 CFR 1910.106 AWAY FROM IGNITION SOURCE, COMBUSTIBLES, OXIDIZING MATERIALS, AND ACID. STORE IN AN AREA EQUIPPED WITH AUTOMATIC SPRINKLERS. LARGE QUA NTITIES SHOULD BE STORED IN METAL TANKS OR DRUMS. GROUND AND BOND METAL CONTAINERS. Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES, ASSUME TO HAVE THE SAME HAZARDS AS FULL CONTAINERS. WEAR APPROPRIATE PROTECTIVE EQUIPMENT W HEN HANDLING METHANOL. FOLLOW ALL FEDERAL, STATE, AND LOCAL REGULATIONS AS WELL AS INSURANCE CODES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DO NOT USE AIR PURIFYING RESPIRATOR. USE APPROPRIATE NIOSH APPROVED SUPPLIED AIR OR SELF CONTAINED RESPIRATOR IN ACCORDANCE WITH 29 CFR 1910.132 AND 1910.134 TO PREVENT OVEREXPOSURE. RESPIRATORS MUST BE SELECTED BASED ON THE AIRBORNE LEVELS FOUND IN THE WORKPLACE AND MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR.. Ventilation:PROVIDE LOCAL VENTILATION TO MAINTAIN EXPOSURE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. USE EXPLOSION PROOF VENTILATION. Protective Gloves:USE NATURAL RUBBER OR NEOPRENE GLOVES. Eye Protection:USE SPLASH PROOF CHEMICAL SAFETY GOGGLES OR APPROPRIATE FULL-FACE RESPIRATOR. Other Protective Equipment:WHERE THERE IS ANY POSSIBILITY THAT AN INDIVIDUAL'S EYES MAY BE EXPOSED TO METHANOL, AN EYEWASH FOUNTAIN (IN ACCORDANCE WITH 29 CFR 1910.151)SHOULD BE WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH THIS CHEMICAL. Supplemental Safety and Health WHERE THERE IS A POSSIBILITY OF EXPOSURE OF AN INDIVIDUAL'S BODY TO METHANOL, FACILITIES FOR QUICKDRENCHING OF THE BODY SHOULD BE PROVIDED(IN ACCORD W/ 29 CFR 1910.151)WITHIN THE IMMEDIATE WORK AREA F OR EMERGENCY USE.INDIVIDUALS SHOULD BE PROVIDED WITH & REQUIRED TO USE IMPERVIOUS CLOTHING IN ACCORD W/ 29 CFR 1910.132. ================== Physical/Chemical Properties ================== HCC:F5 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=64.C, 147.2F Melt/Freeze Pt:=-97.C, -142.6F Vapor Pres:96MMHG AT 20C Vapor Density:1.1AT 20C Spec Gravity:0.792 AT 20/4C(WATER=1.0) Solubility in Water:MISCIBLE Appearance and Odor:CLEAR, COLORLESS LIQUID. FAINT CHARACTERISTIC ALCOHOLIC ODOR Percent Volatiles by Volume:>99.85 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS SUCH AS CHLORINE, NITRIC ACID, DICHLOROMETHANE, CARBON TETRACHLORIDE, ALUMINUM, ZINC, OR METALS THAT DISPLACE HYDROGEN, RUBBER AND RUBBER BASED COATINGS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE AND PERCH Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS Hazardous Decomposition Products:EXCESSIVE HEATING AND/OR INCOMPLETE COMBUSTION WILL PRODUCE CARBON MONOXIDE AND TOXIC VAPORS SUCH AS FORMALDEHYDE. =================== Toxicological Information =================== Toxicological Information:DERMAL RABBIT LD50: 15.8 G/KG. INHALATION CAT LC50 : 65,700 PPM (4.5 HRS) ==================== Disposal Considerations ==================== Waste Disposal Methods:ANY DISPOSAL PRACTICE MUST BE IN COMPLIANCE WITH LOCAL, STATE, AND FEDERAL LAWS AND REGULATIONS (CONTACT LOCAL OR STATE ENVIRONMENTAL AGENCY FOR SPECIFIC RULES). ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 AND 304: NONE. SECTION 311: ACUTE, CHRONIC AND FIRE. SECTION 313: METHANOL. CERCLA: RQ 5,000 LBS. Federal Regulatory Information:RCRA HAZARDOUS WASTE NUMBER: U154. TSCA: METHANOL IS LISTED ON THE TSCA INVENTORY. State Regulatory Information: Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.